How many faradays are required to reduce 1 mol of Cr2O72- to Cr3+
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How many faradays are required to reduce 1 mol of Cr2O to Cr3+ in acid medium?

  • 2

  • 3

  • 5

  • 6


D.

6

Cr2O72- → Cr3+ (Change in +3)

Oxidation number = + 6

Total change in number of electrons = 2 × 3 = 6 mole = 6F


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Nitric acid can be obtained from ammonia via the formations of the intermediate compounds

  • nitric oxide and nitrogen dioxide

  • nitrogen and nitric oxide

  • nitric oxide and dinitrogen pentoxide

  • nitrogen and nitrous oxide


A.

nitric oxide and nitrogen dioxide

Ostwald process of for manufacture of nitric acid,

4NH3 + SO2 800-900°CPt gauge 4NO + 6H2O  (H-21.5 kcal)

2NO + O2 50°C 2NO2

4NO2 + 2H2O + O2 → 4HNO3


Hydrogen peroxide oxidises Fe(CN)6]4- to [Fe(CN)6]3- in acidic medium but reduces [Fe(CN)6]3- to [Fe(CN)6]4- in alkaline medium. The other products formed are, respectively

  • H2O and (H2O + OH-)

  • (H2O + O2) and H2O

  • (H2O + O2) and (H2O + OH-)

  • H2O and (H2O + O2)


D.

H2O and (H2O + O2)


Consider the following reaction,
xMnO subscript 4 superscript minus space plus space yC subscript 2 straight O subscript 4 superscript 2 minus end superscript space plus space zH to the power of plus space rightwards arrow xMn to the power of 2 plus end exponent space plus space 2 yCO subscript 2 space plus space straight z over 2 straight H subscript 2 straight O
The values of x,y and z in the reaction are respectively

  • 5,2 and 16

  • 2,5 and 8

  • 2,5 and 16

  • 2,5 and 16


C.

2,5 and 16

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Which of the following chemical reactions depicts the oxidizing behaviour of H2SO4?

  • 2HI+ H2SO4 →I2 +SO2+2HO

  • Ca(OH)2 +H2SO4 → CaSO4 +2H2O

  • NaCl +H2SO4 → NaHSO4 + HCl

  • NaCl +H2SO4 → NaHSO4 + HCl


A.

2HI+ H2SO4 →I2 +SO2+2HO

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